Single and double-layer composite microwave absorbers with hexaferrite BaZn^sub 0.6^Zr^sub 0.3^X^sub 0.3^Fe^sub 10.8^O^sub 19^ (X = Ti, Ce, Sn) powders

In the present study, substituted barium hexaferrites with the composition BaZn0.6Zr0.3 × 0.3Fe10.8O19 (where X = Ti, Ce, Sn) are prepared with the solid-state reaction method. X-ray diffraction (XRD), scanning electron microscopy (SEM), vibrating sample magnetometry (VSM) and network analysis techniques are used to analyze the crystal phases, morphology, static magnetic and microwave absorption properties, respectively. Based on the recorded results, barium hexaferrite is the major phase obtained after milling of the powders for 20 h, followed by calcination at 1000 °C for 5 h. The morphology of the particles of the substituted ferrite samples is plate-like with hexagonal shape. The microwave absorption in the X-band of epoxy composites loaded with the ferrite fillers, either separately, in pairs or all together, has been extensively investigated. Multicomponent composites filled with the new hexaferrites under study are promising candidates for electromagnetic absorbers in the 8-12 GHz range. It is found that single-layer absorbers of 5 mm thickness with 45 wt% of a binary (Sn and Ti-doped hexaferrite) or ternary filler mixture exhibit the maximum bandwidth of 2.7 GHz at the level of -10 dB or maximum losses of 26.4 dB at 10.8 GHz, respectively.