Fe3O4 Magnetic Nanoparticles (MNPs) as Reusable Catalyst for the Synthesis of Chromene Derivatives Using Multicomponent Reaction of 4‐Hydroxycumarin Basis on Cheletropic Reaction

A series of oxocyclopenta[c]chromenes were synthesized via three component reaction of 4‐hydroxycumarin, dialkyl acetylenedicarboxylate, α‐bromo ketones, and triphenylphosphine in the presence of catalytic amount of Fe3O4 magnetic nanoparticles (MNPs) (15 mol%) under solvent‐free conditions at 70°C....

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Veröffentlicht in:Journal of heterocyclic chemistry 2017-09, Vol.54 (5), p.2906-2911
Hauptverfasser: Ezzatzadeh, Elham, Hossaini, Zinatossadat, Rostamian, Rezvaneh, Vaseghi, Samaneh, Mousavi, Seyyedeh Fatemeh
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Sprache:eng
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Zusammenfassung:A series of oxocyclopenta[c]chromenes were synthesized via three component reaction of 4‐hydroxycumarin, dialkyl acetylenedicarboxylate, α‐bromo ketones, and triphenylphosphine in the presence of catalytic amount of Fe3O4 magnetic nanoparticles (MNPs) (15 mol%) under solvent‐free conditions at 70°C. Facile, green, easy separation of product and catalyst, and high yields of products are advantages of these reactions.
ISSN:0022-152X
1943-5193
DOI:10.1002/jhet.2900