Preparation and characterization of acrylic pressure-sensitive adhesives based on UV and heat curing systems
UV curable acrylic oligomers were prepared for a dual-crosslinking system applicable to general thermosetting acrylic pressure-sensitive adhesives (PSAs). UV-curable oligomers were synthesized using isophorone diisocyanate (IPDI), acrylate monomers, and propylene imine (PI). Acrylate monomers were a...
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Veröffentlicht in: | International journal of adhesion and adhesives 2017-06, Vol.75, p.190-195 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | UV curable acrylic oligomers were prepared for a dual-crosslinking system applicable to general thermosetting acrylic pressure-sensitive adhesives (PSAs). UV-curable oligomers were synthesized using isophorone diisocyanate (IPDI), acrylate monomers, and propylene imine (PI). Acrylate monomers were added at a constant rate to one isocyanate group of IPDI for selective binding, and a polymerization inhibitor was added to prevent polymerization. Also, binding sites bound to the adhesive backbone were generated by adding PI at a constant rate after solvent addition. The synthesized UV oligomers were confirmed by ATR-FTIR spectroscopy. In addition, dual-curable PSA tapes were prepared by simply blending UV curable oligomers and thermosetting acrylic PSAs at room temperature, and their mechanical properties (gel fraction, ball tack, 180° peel strength, and shear adhesion failure temperature (SAFT)) were evaluated based on the volume of UV curable oligomers. |
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ISSN: | 0143-7496 1879-0127 |
DOI: | 10.1016/j.ijadhadh.2017.03.007 |