A study on the synthesis and magnetic properties of the cerium ferrite ceramic

This work is a short report on the synthesis of CeFeO3 ceramic nanopowder from a mixture of CeO2 and Fe2O3 powders via a high energy ball milling process and subsequent heat treatment. Investigation of the magnetic, photocatalytic and absorption properties of CeFeO3 and its potential for colossal di...

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Veröffentlicht in:Journal of alloys and compounds 2017-02, Vol.694, p.800-807
Hauptverfasser: Jabbarzare, Saeid, Abdellahi, Majid, Ghayour, Hamid, Arpanahi, Asiyeh, Khandan, Amirsalar
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Sprache:eng
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Zusammenfassung:This work is a short report on the synthesis of CeFeO3 ceramic nanopowder from a mixture of CeO2 and Fe2O3 powders via a high energy ball milling process and subsequent heat treatment. Investigation of the magnetic, photocatalytic and absorption properties of CeFeO3 and its potential for colossal dielectric constant (CDC) are the main objectives of the present study. The characterization tools were X-ray diffraction (XRD), transmission electron microscopy (TEM), Field emission scanning electron microscopy (FESEM), thermogravimetry (TG), differential thermal analysis (DTA), X-ray photoemission spectroscopy (XPS), ultraviolet–visible spectroscopy (UV–vis) and Image-J software. According to the obtained results, CeFeO3 nanopowder can be raised as a visible light-driven photocatalyst, a semiconductor material with a narrow bandgap and a weak ferromagnetic material. For the first time the CDC behavior of this ceramic was also assessed by XPS analysis which was indicative of a good colossal dielectric constant. The results were also confirmed by the measured dielectric properties. •Synthesis of CeFeO3 ceramic was done via milling and subsequent heat treatment.•A considerable amounts of visible light were absorbed by CeFeO3 nanopowders.•CeFeO3 was considered as a ceramic with a good colossal dielectric constant.•The remanent magnetizations were approximately 0.1 emu/g in all three modes.
ISSN:0925-8388
1873-4669
DOI:10.1016/j.jallcom.2016.10.064