Synthesis of trivalent phosphorus derivatives by light-induced dibromophosphination of akenes

Synthesis of trivalent phosphorus derivatives by light-induced dibromophosphination of akenes

Light-induced dibromophosphination of alkenes was studied. Dehydrobromination of the synthesized bromoalkylphosphonous dibromides gave the corresponding dibromophosphinoalkenes which were converted into alkenylphosphonous acids and their cyclic esters, benzo[1,3,2]dioxaphospholes.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Russian journal of general chemistry 2017-07, Vol.87 (7), p.1527-1530
Hauptverfasser: Krivchun, M. N., Khramchikhin, A. V.
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Dibromides
Esters
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Light-induced dibromophosphination of alkenes was studied. Dehydrobromination of the synthesized bromoalkylphosphonous dibromides gave the corresponding dibromophosphinoalkenes which were converted into alkenylphosphonous acids and their cyclic esters, benzo[1,3,2]dioxaphospholes.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363217070131