Paper-based quasi-solid dye-sensitized solar cells

[Display omitted] •Natural cellulose fibres as photoanode and electrolyte for dye-sensitized solar cells.•TiO2-laden paper foils as photoanodes obtained by papermaking.•Nanoscale microfibrillated cellulose as polymer electrolyte.•Efficiencies as high as 3.55% under 1 sun irradiation.•Stability equal to 96% after 1000h of accelerated aging test. Natural cellulose fibres are proposed as promising components for bioderived photoanodes and polymer electrolytes in dye-sensitized solar cells (DSSCs). In particular, TiO2-laden paper foils, prepared by simple papermaking, can be applied to several substrates (conductive glass or plastics) instead of the high-temperature sintered traditional commercial pastes. In addition, nanoscale microfibrillated cellulose is used as reinforcing filler in acrylate/methacrylate-based thermo-set polymer electrolyte membranes prepared by means of fast, low-cost and green UV-induced free-radical photopolymerization. The laboratory-scale quasi-solid state paper-DSSCs assembled with cellulose-based electrodes and electrolytes guarantee sunlight conversion efficiencies as high as 3.55 and 5.20% at simulated light intensities of 1 and 0.2 sun, respectively, along with an excellent efficiency retention of 96% after 1000h of accelerated aging test. The simple, low cost and green approach here specifically developed opens up intriguing prospects in the design of bio-inspired energy conversion devices showing high performance, outstanding durability and truly sustainable characteristics.