Corrosion behavior of Al-3.0 wt%Mg alloy in NaCl solution under magnetic field

The influences of applied magnetic field on the corrosion behavior of Al-3.0 wt%Mg alloy in 3.5 wt% NaCl solution were investigated by electrochemical measurements,scanning electron microscopy(SEM)and energy-dispersive spectroscopy(EDS).Stochastic analysis was applied to investigate the influences o...

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Veröffentlicht in:Rare metals 2017-08, Vol.36 (8), p.627-634
Hauptverfasser: Zhang, Xin, Wang, Ze-Hua, Zhou, Ze-Hua, Xu, Jian-Ming, Zhong, Zhao-Jun, Yuan, Huan-Long
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Sprache:eng
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Zusammenfassung:The influences of applied magnetic field on the corrosion behavior of Al-3.0 wt%Mg alloy in 3.5 wt% NaCl solution were investigated by electrochemical measurements,scanning electron microscopy(SEM)and energy-dispersive spectroscopy(EDS).Stochastic analysis was applied to investigate the influences of applied magnetic field.The results indicate that the application of horizontal magnetic field of 0.4 T would increase the pitting corrosion potential(E_(pit)),decrease the corrosion current density(i_(corr)),prolong the pit initiation time,slow down the pit generation rate and inhibit the growth of pitting of the tested alloys in 3.5 wt% NaCl solution.The applied magnetic field would also change the mechanism of pit initiation of Al-3.0 wt%Mg alloy from A_3 model(without magnetic field)to A_3+A_4 model(with magnetic field).The intermediate product Al_((ad))~+ is the paramagnetic ion that would be influenced by magnetic field sensitively.
ISSN:1001-0521
1867-7185
DOI:10.1007/s12598-016-0785-5