Metal Trimethylsilylthiolates for the Synthesis of Trinuclear MnPd2 Complexes

Metal Trimethylsilylthiolates for the Synthesis of Trinuclear MnPd2 Complexes

The manganese(II)‐palladium(II)‐sulfide complex [MnCl2(μ3‐S)2Pd2(dppp)2] (2) was prepared from the reaction of [PdCl2(dppp)] with [Li(N,N'‐tmeda)]2[Mn(SSiMe3)4] (2) in a 2:1 ratio under mild conditions. The new trimethylsilylthiolate complex [Pd(dppp)(SSiMe3)2] (3) was synthesized from the reac...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Zeitschrift für anorganische und allgemeine Chemie (1950) 2017-08, Vol.643 (15), p.973-979
Hauptverfasser: Rozic, Kyle N. W., Azizpoor Fard, Mahmood, Khalili Najafabadi, Bahareh, Corrigan, John F.
Format: Artikel
Sprache:eng
Schlagworte:
Chemical synthesis
Manganese
Palladium
Trimethylsilylthiolate complex
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The manganese(II)‐palladium(II)‐sulfide complex [MnCl2(μ3‐S)2Pd2(dppp)2] (2) was prepared from the reaction of [PdCl2(dppp)] with [Li(N,N'‐tmeda)]2[Mn(SSiMe3)4] (2) in a 2:1 ratio under mild conditions. The new trimethylsilylthiolate complex [Pd(dppp)(SSiMe3)2] (3) was synthesized from the reaction of [Pd(dppp)(OAc)2] with two equivalents of Li[SSiMe3]; this was then used in a reaction with [Mn(CH3CN)2(OTf)2] to form the manganese(II)‐palladium(II)‐sulfide cluster [Mn(OTf)(thf)2(μ3‐S)2Pd2(dppp)2]OTf (4).
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.201700179