Inside Back Cover: Noninnocent [beta]-Diiminate Ligands: Redox Activity of a Bis(alkylimidazole)methane Ligand in Cobalt and Zinc Complexes

The first example of a redox non-innocent [beta]-diketiminate-type ligand, bis(1-methyl-4,5-diphenyl-1H-imidazol-2-yl)methane anion, BMIMPh2-, is presented. In homoleptic metal complexes, these ligands are susceptible toward oxidation, covering three different oxidation states. The redox behavior of...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry : a European journal 2017-08, Vol.23 (45), p.10931
Hauptverfasser: Ghosh, Pradip, Naastepad, Richard, Riemersma, Charl F, Lutz, Martin, Moret, Marc-Etienne, KleinGebbink, Robertus J M
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The first example of a redox non-innocent [beta]-diketiminate-type ligand, bis(1-methyl-4,5-diphenyl-1H-imidazol-2-yl)methane anion, BMIMPh2-, is presented. In homoleptic metal complexes, these ligands are susceptible toward oxidation, covering three different oxidation states. The redox behavior of complexes featuring BMIMPh2- or related ligands are expected be a versatile tool in contemporary research within the context of chemical catalysis or activation of small molecules. More information can be found in the Communication by R.J.M. KleinGebbink etal. on page 10732. (Background illustration: Invisible_studio - Freepik.com; Scientific figures: P. Ghosh).
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201702831