Synergistic effect of temperature and HCl concentration on the degradation of AISI 410 stainless steel

•Corrosion domains are established for 410 SS as a function of [HCl] and temperature.•Synergistic effect of hydrogen and chloride ions is found for passive film breakdown.•Permanent uniform degradation of passive film occurs above critical temperature.•Metastable pitting initiates from non-metallic...

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Veröffentlicht in:Corrosion science 2017-07, Vol.122, p.41-52
Hauptverfasser: Krell, Paul D., Li, Shengxi, Cong, Hongbo
Format: Artikel
Sprache:eng
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Zusammenfassung:•Corrosion domains are established for 410 SS as a function of [HCl] and temperature.•Synergistic effect of hydrogen and chloride ions is found for passive film breakdown.•Permanent uniform degradation of passive film occurs above critical temperature.•Metastable pitting initiates from non-metallic inclusions below critical temperature.•Sigma phase particles are identified in 410 SS by TEM/SAED and remain uncorroded. The corrosion behavior of AISI 410 stainless steel was investigated in relatively dilute HCl solutions with different concentrations and temperature levels. General corrosion occurred at pH
ISSN:0010-938X
1879-0496
DOI:10.1016/j.corsci.2017.03.027