Oriented Two‐Dimensional Porous Organic Cage Crystals
The formation of two‐dimensional (2D) oriented porous organic cage crystals (consisting of imine‐based tetrahedral molecules) on various substrates (such as silicon wafers and glass) by solution‐processing is reported. Insight into the crystallinity, preferred orientation, and cage crystal growth wa...
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| Veröffentlicht in: | Angewandte Chemie 2017-08, Vol.129 (32), p.9519-9523 |
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| container_title | Angewandte Chemie |
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| creator | Jiang, Shan Song, Qilei Massey, Alan Chong, Samantha Y. Chen, Linjiang Sun, Shijing Hasell, Tom Raval, Rasmita Sivaniah, Easan Cheetham, Anthony K. Cooper, Andrew I. |
| description | The formation of two‐dimensional (2D) oriented porous organic cage crystals (consisting of imine‐based tetrahedral molecules) on various substrates (such as silicon wafers and glass) by solution‐processing is reported. Insight into the crystallinity, preferred orientation, and cage crystal growth was obtained by experimental and computational techniques. For the first time, structural defects in porous molecular materials were observed directly and the defect concentration could be correlated with crystal growth rate. These oriented crystals suggest potential for future applications, such as solution‐processable molecular crystalline 2D membranes for molecular separations.
Kristalliner Sechskant: Poröse organische 2D‐Käfigkristalle aus Imin‐basierten tetraedrischen Molekülen wurden mit einer neuartigen hexagonalen Morphologie auf verschiedenen Substraten wie Siliciumwafern und Glas hergestellt. Das kontrollierte Wachstum und die Ausrichtung der Käfigkristalle wurden untersucht, ebenso die molekularen Defekte. |
| doi_str_mv | 10.1002/ange.201704579 |
| format | Article |
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Kristalliner Sechskant: Poröse organische 2D‐Käfigkristalle aus Imin‐basierten tetraedrischen Molekülen wurden mit einer neuartigen hexagonalen Morphologie auf verschiedenen Substraten wie Siliciumwafern und Glas hergestellt. Das kontrollierte Wachstum und die Ausrichtung der Käfigkristalle wurden untersucht, ebenso die molekularen Defekte.</description><identifier>ISSN: 0044-8249</identifier><identifier>EISSN: 1521-3757</identifier><identifier>DOI: 10.1002/ange.201704579</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Cages ; Chemistry ; Computer applications ; Crystal defects ; Crystal growth ; Crystallinity ; Crystals ; Growth rate ; Kristalldefekte ; Membranes ; Mikroporöse Materialien ; Orientierte molekulare Kristalle ; Porous materials ; Poröse organische Käfige ; Preferred orientation ; Silicon ; Silicon substrates ; Silicon wafers ; Substrates ; Trennmembranen ; Wafers</subject><ispartof>Angewandte Chemie, 2017-08, Vol.129 (32), p.9519-9523</ispartof><rights>2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.</rights><rights>2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2029-ebd069cb3941bb61b6922762e87483a78e47ebcda0f5e7d77d2f0e6ce0873aa33</citedby><cites>FETCH-LOGICAL-c2029-ebd069cb3941bb61b6922762e87483a78e47ebcda0f5e7d77d2f0e6ce0873aa33</cites><orcidid>0000-0001-7293-8370 ; 0000-0001-8570-3626 ; 0000-0002-3095-875X ; 0000-0003-4736-0604</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fange.201704579$$EPDF$$P50$$Gwiley$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fange.201704579$$EHTML$$P50$$Gwiley$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Jiang, Shan</creatorcontrib><creatorcontrib>Song, Qilei</creatorcontrib><creatorcontrib>Massey, Alan</creatorcontrib><creatorcontrib>Chong, Samantha Y.</creatorcontrib><creatorcontrib>Chen, Linjiang</creatorcontrib><creatorcontrib>Sun, Shijing</creatorcontrib><creatorcontrib>Hasell, Tom</creatorcontrib><creatorcontrib>Raval, Rasmita</creatorcontrib><creatorcontrib>Sivaniah, Easan</creatorcontrib><creatorcontrib>Cheetham, Anthony K.</creatorcontrib><creatorcontrib>Cooper, Andrew I.</creatorcontrib><title>Oriented Two‐Dimensional Porous Organic Cage Crystals</title><title>Angewandte Chemie</title><description>The formation of two‐dimensional (2D) oriented porous organic cage crystals (consisting of imine‐based tetrahedral molecules) on various substrates (such as silicon wafers and glass) by solution‐processing is reported. Insight into the crystallinity, preferred orientation, and cage crystal growth was obtained by experimental and computational techniques. For the first time, structural defects in porous molecular materials were observed directly and the defect concentration could be correlated with crystal growth rate. These oriented crystals suggest potential for future applications, such as solution‐processable molecular crystalline 2D membranes for molecular separations.
Kristalliner Sechskant: Poröse organische 2D‐Käfigkristalle aus Imin‐basierten tetraedrischen Molekülen wurden mit einer neuartigen hexagonalen Morphologie auf verschiedenen Substraten wie Siliciumwafern und Glas hergestellt. Das kontrollierte Wachstum und die Ausrichtung der Käfigkristalle wurden untersucht, ebenso die molekularen Defekte.</description><subject>Cages</subject><subject>Chemistry</subject><subject>Computer applications</subject><subject>Crystal defects</subject><subject>Crystal growth</subject><subject>Crystallinity</subject><subject>Crystals</subject><subject>Growth rate</subject><subject>Kristalldefekte</subject><subject>Membranes</subject><subject>Mikroporöse Materialien</subject><subject>Orientierte molekulare Kristalle</subject><subject>Porous materials</subject><subject>Poröse organische Käfige</subject><subject>Preferred orientation</subject><subject>Silicon</subject><subject>Silicon substrates</subject><subject>Silicon wafers</subject><subject>Substrates</subject><subject>Trennmembranen</subject><subject>Wafers</subject><issn>0044-8249</issn><issn>1521-3757</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><sourceid>WIN</sourceid><recordid>eNqFkM1OwkAURidGExHdum7iunjnp72dJamIJkRc4HoybW9JCXRwBkK68xF8Rp_EEowuXX2bc25uDmO3HEYcQNzbdkkjARxBJajP2IAngscSEzxnAwCl4kwofcmuQlgBQCpQDxjOfUPtjqpocXBfH58PzYba0LjWrqNX590-RHO_tG1TRrldUpT7LuzsOlyzi7ofuvnZIXt7nCzyp3g2nz7n41lcChA6pqKCVJeF1IoXRcqLVAuBqaAMVSYtZqSQirKyUCeEFWIlaqC0JMhQWivlkN2d7m69e99T2JmV2_v-u2C4FjLligvsqdGJKr0LwVNttr7ZWN8ZDuYYxxzjmN84vaBPwqFZU_cPbcYv08mf-w3cRmjL</recordid><startdate>20170801</startdate><enddate>20170801</enddate><creator>Jiang, Shan</creator><creator>Song, Qilei</creator><creator>Massey, Alan</creator><creator>Chong, Samantha Y.</creator><creator>Chen, Linjiang</creator><creator>Sun, Shijing</creator><creator>Hasell, Tom</creator><creator>Raval, Rasmita</creator><creator>Sivaniah, Easan</creator><creator>Cheetham, Anthony K.</creator><creator>Cooper, Andrew I.</creator><general>Wiley Subscription Services, Inc</general><scope>24P</scope><scope>WIN</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-7293-8370</orcidid><orcidid>https://orcid.org/0000-0001-8570-3626</orcidid><orcidid>https://orcid.org/0000-0002-3095-875X</orcidid><orcidid>https://orcid.org/0000-0003-4736-0604</orcidid></search><sort><creationdate>20170801</creationdate><title>Oriented Two‐Dimensional Porous Organic Cage Crystals</title><author>Jiang, Shan ; Song, Qilei ; Massey, Alan ; Chong, Samantha Y. ; Chen, Linjiang ; Sun, Shijing ; Hasell, Tom ; Raval, Rasmita ; Sivaniah, Easan ; Cheetham, Anthony K. ; Cooper, Andrew I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2029-ebd069cb3941bb61b6922762e87483a78e47ebcda0f5e7d77d2f0e6ce0873aa33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Cages</topic><topic>Chemistry</topic><topic>Computer applications</topic><topic>Crystal defects</topic><topic>Crystal growth</topic><topic>Crystallinity</topic><topic>Crystals</topic><topic>Growth rate</topic><topic>Kristalldefekte</topic><topic>Membranes</topic><topic>Mikroporöse Materialien</topic><topic>Orientierte molekulare Kristalle</topic><topic>Porous materials</topic><topic>Poröse organische Käfige</topic><topic>Preferred orientation</topic><topic>Silicon</topic><topic>Silicon substrates</topic><topic>Silicon wafers</topic><topic>Substrates</topic><topic>Trennmembranen</topic><topic>Wafers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jiang, Shan</creatorcontrib><creatorcontrib>Song, Qilei</creatorcontrib><creatorcontrib>Massey, Alan</creatorcontrib><creatorcontrib>Chong, Samantha Y.</creatorcontrib><creatorcontrib>Chen, Linjiang</creatorcontrib><creatorcontrib>Sun, Shijing</creatorcontrib><creatorcontrib>Hasell, Tom</creatorcontrib><creatorcontrib>Raval, Rasmita</creatorcontrib><creatorcontrib>Sivaniah, Easan</creatorcontrib><creatorcontrib>Cheetham, Anthony K.</creatorcontrib><creatorcontrib>Cooper, Andrew I.</creatorcontrib><collection>Wiley-Blackwell Open Access Titles</collection><collection>Wiley Free Content</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Angewandte Chemie</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jiang, Shan</au><au>Song, Qilei</au><au>Massey, Alan</au><au>Chong, Samantha Y.</au><au>Chen, Linjiang</au><au>Sun, Shijing</au><au>Hasell, Tom</au><au>Raval, Rasmita</au><au>Sivaniah, Easan</au><au>Cheetham, Anthony K.</au><au>Cooper, Andrew I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Oriented Two‐Dimensional Porous Organic Cage Crystals</atitle><jtitle>Angewandte Chemie</jtitle><date>2017-08-01</date><risdate>2017</risdate><volume>129</volume><issue>32</issue><spage>9519</spage><epage>9523</epage><pages>9519-9523</pages><issn>0044-8249</issn><eissn>1521-3757</eissn><abstract>The formation of two‐dimensional (2D) oriented porous organic cage crystals (consisting of imine‐based tetrahedral molecules) on various substrates (such as silicon wafers and glass) by solution‐processing is reported. Insight into the crystallinity, preferred orientation, and cage crystal growth was obtained by experimental and computational techniques. For the first time, structural defects in porous molecular materials were observed directly and the defect concentration could be correlated with crystal growth rate. These oriented crystals suggest potential for future applications, such as solution‐processable molecular crystalline 2D membranes for molecular separations.
Kristalliner Sechskant: Poröse organische 2D‐Käfigkristalle aus Imin‐basierten tetraedrischen Molekülen wurden mit einer neuartigen hexagonalen Morphologie auf verschiedenen Substraten wie Siliciumwafern und Glas hergestellt. Das kontrollierte Wachstum und die Ausrichtung der Käfigkristalle wurden untersucht, ebenso die molekularen Defekte.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/ange.201704579</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0001-7293-8370</orcidid><orcidid>https://orcid.org/0000-0001-8570-3626</orcidid><orcidid>https://orcid.org/0000-0002-3095-875X</orcidid><orcidid>https://orcid.org/0000-0003-4736-0604</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Cages Chemistry Computer applications Crystal defects Crystal growth Crystallinity Crystals Growth rate Kristalldefekte Membranes Mikroporöse Materialien Orientierte molekulare Kristalle Porous materials Poröse organische Käfige Preferred orientation Silicon Silicon substrates Silicon wafers Substrates Trennmembranen Wafers |
| title | Oriented Two‐Dimensional Porous Organic Cage Crystals |
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