Oriented Two‐Dimensional Porous Organic Cage Crystals

The formation of two‐dimensional (2D) oriented porous organic cage crystals (consisting of imine‐based tetrahedral molecules) on various substrates (such as silicon wafers and glass) by solution‐processing is reported. Insight into the crystallinity, preferred orientation, and cage crystal growth was obtained by experimental and computational techniques. For the first time, structural defects in porous molecular materials were observed directly and the defect concentration could be correlated with crystal growth rate. These oriented crystals suggest potential for future applications, such as solution‐processable molecular crystalline 2D membranes for molecular separations. Kristalliner Sechskant: Poröse organische 2D‐Käfigkristalle aus Imin‐basierten tetraedrischen Molekülen wurden mit einer neuartigen hexagonalen Morphologie auf verschiedenen Substraten wie Siliciumwafern und Glas hergestellt. Das kontrollierte Wachstum und die Ausrichtung der Käfigkristalle wurden untersucht, ebenso die molekularen Defekte.