Halocyclization of products of allyl isothiocyanate addition to acyclic methylene active compounds

Halocyclization of products of allyl isothiocyanate addition to acyclic methylene active compounds

Products of allyl isothiocyanate addition to methylene active compounds, salt-like N -allyl- N,S -ketenacetals or N -allylthioamides, react with iodine, bromine or N -bromosuccinimide with the formation of derivatives of 2-ylidene-5-halomethylthiazolidines. A dependence was found of isomeric composi...

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Veröffentlicht in:Russian journal of organic chemistry 2017, Vol.53 (5), p.709-716
Hauptverfasser: Litvinchuk, M. B., Bentya, A. V., Slyvka, N. Yu, Vovk, M. V.
Format: Artikel
Sprache:eng
Schlagworte:
Allyl isothiocyanate
Bromine compounds
Chemistry
Chemistry and Materials Science
Derivatives
Iodine
Methylene
Organic Chemistry
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Beschreibung
Zusammenfassung:Products of allyl isothiocyanate addition to methylene active compounds, salt-like N -allyl- N,S -ketenacetals or N -allylthioamides, react with iodine, bromine or N -bromosuccinimide with the formation of derivatives of 2-ylidene-5-halomethylthiazolidines. A dependence was found of isomeric composition of obtained thiazolidines on the solvent nature.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428017050104