Frontispiece: 10‐Silacorroles Exhibiting Near‐Infrared Absorption and Emission

Jump to 1000 nm! In this picture, the effect of heteroatoms in 10‐heterocorroles, heteroatom‐containing porphyrin analogs, on their absorption wavelengths is illustrated. As compared to several other elements incorporated into the 10‐heterocorrole skeleton, silicon is powerful enough to push the abs...

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Veröffentlicht in:Chemistry : a European journal 2017-06, Vol.23 (33), p.n/a
Hauptverfasser: Omori, Hiroto, Hiroto, Satoru, Shinokubo, Hiroshi
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Hiroto, Satoru
Shinokubo, Hiroshi
description Jump to 1000 nm! In this picture, the effect of heteroatoms in 10‐heterocorroles, heteroatom‐containing porphyrin analogs, on their absorption wavelengths is illustrated. As compared to several other elements incorporated into the 10‐heterocorrole skeleton, silicon is powerful enough to push the absorption band into the near‐infrared (NIR) region through σ*–π* conjugation. NIR absorption and emission dyes are promising materials for applications in bioimaging, photodynamic therapy, and solar energy conversion. For more information, see the Communication by H. Omori, S. Hiroto, and H. Shinokubo on page 7866 ff.
doi_str_mv 10.1002/chem.201783363
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subjects 10-heterocorroles
Absorption
Absorption spectra
Analogs
Chemistry
Conjugation
Direct power generation
Dyes
dyes/pigments
Emission
Energy
Energy conversion
I.R. radiation
Infrared absorption
Medical imaging
Near infrared radiation
NIR emission
Photodynamic therapy
porphyrinoids
Silicon
Solar energy
Solar energy conversion
Wavelengths
title Frontispiece: 10‐Silacorroles Exhibiting Near‐Infrared Absorption and Emission
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