Back Cover: Synthesis of Tetrazino-tetrazine 1,3,6,8-Tetraoxide (TTTO) (Angew. Chem. Int. Ed. 38/2016)

Back Cover: Synthesis of Tetrazino-tetrazine 1,3,6,8-Tetraoxide (TTTO) (Angew. Chem. Int. Ed. 38/2016)

A high‐energy molecule can be thermally stable if its structure shows alternating charges. In their Communication on page 11472 ff., A. M. Churakov et al. report the synthesis of a new nitrogen system 1,2,3,4‐tetrazino[5,6‐e]‐1,2,3,4‐tetrazine‐1,3,6,8‐tetraoxide. The synthetic strategy was based on...

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Veröffentlicht in:Angewandte Chemie International Edition 2016-09, Vol.55 (38), p.11688-11688
Hauptverfasser: Klenov, Michael S., Guskov, Alexey A., Anikin, Oleg V., Churakov, Aleksandr M., Strelenko, Yurii A., Fedyanin, Ivan V., Lyssenko, Konstantin A., Tartakovsky, Vladimir A.
Format: Artikel
Sprache:eng
Schlagworte:
Chemical synthesis
Coupling
Coupling (molecular)
cyclization
Dioxides
energetic materials
Energy
Ions
Molecular structure
Nitrogen
nitrogen heterocycles
tetrazines
Thermal stability
total synthesis
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Zusammenfassung:A high‐energy molecule can be thermally stable if its structure shows alternating charges. In their Communication on page 11472 ff., A. M. Churakov et al. report the synthesis of a new nitrogen system 1,2,3,4‐tetrazino[5,6‐e]‐1,2,3,4‐tetrazine‐1,3,6,8‐tetraoxide. The synthetic strategy was based on the sequential closure of two 1,2,3,4‐tetrazine 1,3‐dioxide rings by the generation of oxodiazonium ions and their intramolecular coupling with tert‐butyl‐NNO‐azoxy groups.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201606541