A Valuable Upgrade to the Portfolio of Cycloaddition Reactions
Knitting: Recently Antonchick and Manna described a unique annulation that knits together three acetophenones to construct cyclopropanes. The cascade is mediated by organocopper and free radical species, and amounts to the first known [1+1+1] cyclotrimerization. It works well for ketones having elec...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2016-06, Vol.55 (25), p.7034-7036 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Walton, John C. |
| description | Knitting: Recently Antonchick and Manna described a unique annulation that knits together three acetophenones to construct cyclopropanes. The cascade is mediated by organocopper and free radical species, and amounts to the first known [1+1+1] cyclotrimerization. It works well for ketones having electron‐deficient or electron‐rich substituents in their aryl rings. DTBP=di‐tert‐butylperoxide. |
| doi_str_mv | 10.1002/anie.201602891 |
| format | Article |
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DTBP=di‐tert‐butylperoxide.</description><subject>Aromatic compounds</subject><subject>carbocycles</subject><subject>Chemical reactions</subject><subject>copper</subject><subject>Cycloaddition</subject><subject>cyclotrimerization</subject><subject>Ketones</subject><subject>Knitting</subject><subject>Organic chemistry</subject><subject>Organic compounds</subject><subject>radicals</subject><subject>synthetic methods</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkEtPwkAUhSdGI4puXZomrovzfmxMCAEkIWiM4HIybWe0WBictlH-vSVF4kpX9yy-893kAHCFYA9BiG_NOrc9DBGHWCp0BM4QwygmQpDjJlNCYiEZ6oDzslw2vJSQn4IOFohwyOkZuOtHC1PUJilsNN-8BpPZqPJR9WajRx8q54vcR95Fg21aeJNleZX7dfRkTboL5QU4caYo7eX-dsF8NHwe3MfTh_Fk0J_GKaUExTRTjsKUUIwhT43EBFplKeVMZVA6kWLIskRKZ1NnnMWKNwkb0Txk1CSEdMFN690E_1HbstJLX4d181IjBTnHFBL1JyUUg0wpwhqq11Jp8GUZrNObkK9M2GoE9W5UvRtVH0ZtCtd7bZ2sbHbAf1ZsANUCn3lht__odH82Gf6Wx203Lyv7deia8K65IILpl9lYj9B4MSNypBX5Br_ikJQ</recordid><startdate>20160613</startdate><enddate>20160613</enddate><creator>Walton, John C.</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><orcidid>https://orcid.org/0000-0003-2746-6276</orcidid></search><sort><creationdate>20160613</creationdate><title>A Valuable Upgrade to the Portfolio of Cycloaddition Reactions</title><author>Walton, John C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4431-4d9f40c342206ca8230e9e44659d08f7c205db88fecfafe296fec2a7add54ab33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Aromatic compounds</topic><topic>carbocycles</topic><topic>Chemical reactions</topic><topic>copper</topic><topic>Cycloaddition</topic><topic>cyclotrimerization</topic><topic>Ketones</topic><topic>Knitting</topic><topic>Organic chemistry</topic><topic>Organic compounds</topic><topic>radicals</topic><topic>synthetic methods</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Walton, John C.</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Walton, John C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Valuable Upgrade to the Portfolio of Cycloaddition Reactions</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. 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| language | eng |
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| source | Wiley Journals |
| subjects | Aromatic compounds carbocycles Chemical reactions copper Cycloaddition cyclotrimerization Ketones Knitting Organic chemistry Organic compounds radicals synthetic methods |
| title | A Valuable Upgrade to the Portfolio of Cycloaddition Reactions |
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