Lithium-Catalyzed Carbon Aerogel and Its Possible Application in Energy Storage Materials

A lithium-based catalyst for carbon aerogel compounds and carbon nanotubes synthesis was used. Lithium hydroxide-catalyzed and CNT-modified carbon aerogel was compared to traditionally synthesized sodium carbonate-catalyzed carbon aerogel, as well as to the same material modified with CNT to evaluat...

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Veröffentlicht in:Journal of electronic materials 2017-07, Vol.46 (7), p.4612-4617
Hauptverfasser: Ciszewski, Mateusz, Szatkowska, Elżbieta, Koszorek, Andrzej
Format: Artikel
Sprache:eng
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Zusammenfassung:A lithium-based catalyst for carbon aerogel compounds and carbon nanotubes synthesis was used. Lithium hydroxide-catalyzed and CNT-modified carbon aerogel was compared to traditionally synthesized sodium carbonate-catalyzed carbon aerogel, as well as to the same material modified with CNT to evaluate the real effect of lithium hydroxide addition. Enhancement in the specific surface area from 498 m 2 /g to 786 m 2 /g and significant change in pore size distribution were observed. Low temperature, supercritical drying in carbon dioxide was used to prepare an organic aerogel with subsequent pyrolysis in an inert gas flow to convert it into carbon aerogel. The as-obtained material was examined with respect to energy storage applications, i.e. symmetric hybrid supercapacitors. It was shown that lithium hydroxide was responsible for shorter gelation time, increased specific surface area, and a greater number of micropores within the structure. For both reference materials prepared using sodium carbonate, quite different data were recorded. It was presented that the proper choice of carbon matrix should combine both high specific surface area and appropriate pore size distribution. High surface area and a relatively large number of micropores were responsible for specific capacity loss.
ISSN:0361-5235
1543-186X
DOI:10.1007/s11664-017-5454-4