Copolymers based on (p-vinylphenyl)cyclopropylmethyl chlorocinnamate and methyl methacrylate
—Copolymers of ( p -vinylphenyl)cyclopropylmethyl chlorocinnamate with methyl methacrylate were prepared by radical copolymerization. The copolymerization constants were determined, and the Alfrey–Price Q–e parameters were calculated. The possibility of photochemical cross-linking of the copolymer v...
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| Veröffentlicht in: | Russian journal of applied chemistry 2017, Vol.90 (2), p.262-266 |
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| container_end_page | 266 |
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| container_issue | 2 |
| container_start_page | 262 |
| container_title | Russian journal of applied chemistry |
| container_volume | 90 |
| creator | Guliyev, K. G. Aliyeva, A. M. Ponomareva, G. Z. Sadygova, A. I. Mamedli, S. B. Guliyev, A. M. |
| description | —Copolymers of (
p
-vinylphenyl)cyclopropylmethyl chlorocinnamate with methyl methacrylate were prepared by radical copolymerization. The copolymerization constants were determined, and the Alfrey–Price Q–e parameters were calculated. The possibility of photochemical cross-linking of the copolymer via double bond conjugated with the carbonyl group in the chlorocinnamate moiety and via the cyclopropane ring was demonstrated. The copolymer obtained exhibits sufficiently high photosensitivity (54.5 cm
2
J
–1
) and high refractive index (
n
D
20
1.5890), which opens prospects for using it as a photosensitive base of negative photoresists and in optics. |
| doi_str_mv | 10.1134/S1070427217020161 |
| format | Article |
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p
-vinylphenyl)cyclopropylmethyl chlorocinnamate with methyl methacrylate were prepared by radical copolymerization. The copolymerization constants were determined, and the Alfrey–Price Q–e parameters were calculated. The possibility of photochemical cross-linking of the copolymer via double bond conjugated with the carbonyl group in the chlorocinnamate moiety and via the cyclopropane ring was demonstrated. The copolymer obtained exhibits sufficiently high photosensitivity (54.5 cm
2
J
–1
) and high refractive index (
n
D
20
1.5890), which opens prospects for using it as a photosensitive base of negative photoresists and in optics.</description><identifier>ISSN: 1070-4272</identifier><identifier>EISSN: 1608-3296</identifier><identifier>DOI: 10.1134/S1070427217020161</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Carbonyls ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Copolymerization ; Copolymers ; Crosslinking ; Cyclopropane ; Industrial Chemistry/Chemical Engineering ; Macromolecular Compounds and Polymeric Materials ; Mathematical analysis ; Photoresists ; Photosensitivity ; Polymethyl methacrylate ; Refractivity</subject><ispartof>Russian journal of applied chemistry, 2017, Vol.90 (2), p.262-266</ispartof><rights>Pleiades Publishing, Ltd. 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c305t-6a1722a3b5e52fa4800b35df32cdb86b64b3c83541dbe73320b013e7f1c2212d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070427217020161$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070427217020161$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Guliyev, K. G.</creatorcontrib><creatorcontrib>Aliyeva, A. M.</creatorcontrib><creatorcontrib>Ponomareva, G. Z.</creatorcontrib><creatorcontrib>Sadygova, A. I.</creatorcontrib><creatorcontrib>Mamedli, S. B.</creatorcontrib><creatorcontrib>Guliyev, A. M.</creatorcontrib><title>Copolymers based on (p-vinylphenyl)cyclopropylmethyl chlorocinnamate and methyl methacrylate</title><title>Russian journal of applied chemistry</title><addtitle>Russ J Appl Chem</addtitle><description>—Copolymers of (
p
-vinylphenyl)cyclopropylmethyl chlorocinnamate with methyl methacrylate were prepared by radical copolymerization. The copolymerization constants were determined, and the Alfrey–Price Q–e parameters were calculated. The possibility of photochemical cross-linking of the copolymer via double bond conjugated with the carbonyl group in the chlorocinnamate moiety and via the cyclopropane ring was demonstrated. The copolymer obtained exhibits sufficiently high photosensitivity (54.5 cm
2
J
–1
) and high refractive index (
n
D
20
1.5890), which opens prospects for using it as a photosensitive base of negative photoresists and in optics.</description><subject>Carbonyls</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Copolymerization</subject><subject>Copolymers</subject><subject>Crosslinking</subject><subject>Cyclopropane</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Macromolecular Compounds and Polymeric Materials</subject><subject>Mathematical analysis</subject><subject>Photoresists</subject><subject>Photosensitivity</subject><subject>Polymethyl methacrylate</subject><subject>Refractivity</subject><issn>1070-4272</issn><issn>1608-3296</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1UE1LAzEQDaJgrf4Abwte9LA6k-xmt0cpVoWCB_UmLEk2a1uyyZpshfx7U9qDIF7mDfM-ZhhCLhFuEVlx94pQQUErihVQQI5HZIIc6pzRGT9OfaLzHX9KzkLYAMCM83pCPuZucCb22odMiqDbzNnsesi_1zaaYaVTvVFRGTd4N0TT63EVTaZWxnmn1taKXow6E7bNDtQOhPLRpPk5OemECfrigFPyvnh4mz_ly5fH5_n9MlcMyjHnAitKBZOlLmknihpAsrLtGFWtrLnkhWSqZmWBrdQVYxQkINNVh4pSpC2bkqt9bjrya6vD2Gzc1tu0ssEZFHWNADSpcK9S3oXgddcMft0LHxuEZvfE5s8Tk4fuPSFp7af2v5L_Nf0AZNZ0cw</recordid><startdate>2017</startdate><enddate>2017</enddate><creator>Guliyev, K. G.</creator><creator>Aliyeva, A. M.</creator><creator>Ponomareva, G. Z.</creator><creator>Sadygova, A. I.</creator><creator>Mamedli, S. B.</creator><creator>Guliyev, A. M.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2017</creationdate><title>Copolymers based on (p-vinylphenyl)cyclopropylmethyl chlorocinnamate and methyl methacrylate</title><author>Guliyev, K. G. ; Aliyeva, A. M. ; Ponomareva, G. Z. ; Sadygova, A. I. ; Mamedli, S. B. ; Guliyev, A. M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c305t-6a1722a3b5e52fa4800b35df32cdb86b64b3c83541dbe73320b013e7f1c2212d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Carbonyls</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Copolymerization</topic><topic>Copolymers</topic><topic>Crosslinking</topic><topic>Cyclopropane</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Macromolecular Compounds and Polymeric Materials</topic><topic>Mathematical analysis</topic><topic>Photoresists</topic><topic>Photosensitivity</topic><topic>Polymethyl methacrylate</topic><topic>Refractivity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Guliyev, K. G.</creatorcontrib><creatorcontrib>Aliyeva, A. M.</creatorcontrib><creatorcontrib>Ponomareva, G. Z.</creatorcontrib><creatorcontrib>Sadygova, A. I.</creatorcontrib><creatorcontrib>Mamedli, S. B.</creatorcontrib><creatorcontrib>Guliyev, A. M.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of applied chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Guliyev, K. G.</au><au>Aliyeva, A. M.</au><au>Ponomareva, G. Z.</au><au>Sadygova, A. I.</au><au>Mamedli, S. B.</au><au>Guliyev, A. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Copolymers based on (p-vinylphenyl)cyclopropylmethyl chlorocinnamate and methyl methacrylate</atitle><jtitle>Russian journal of applied chemistry</jtitle><stitle>Russ J Appl Chem</stitle><date>2017</date><risdate>2017</risdate><volume>90</volume><issue>2</issue><spage>262</spage><epage>266</epage><pages>262-266</pages><issn>1070-4272</issn><eissn>1608-3296</eissn><abstract>—Copolymers of (
p
-vinylphenyl)cyclopropylmethyl chlorocinnamate with methyl methacrylate were prepared by radical copolymerization. The copolymerization constants were determined, and the Alfrey–Price Q–e parameters were calculated. The possibility of photochemical cross-linking of the copolymer via double bond conjugated with the carbonyl group in the chlorocinnamate moiety and via the cyclopropane ring was demonstrated. The copolymer obtained exhibits sufficiently high photosensitivity (54.5 cm
2
J
–1
) and high refractive index (
n
D
20
1.5890), which opens prospects for using it as a photosensitive base of negative photoresists and in optics.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070427217020161</doi><tpages>5</tpages></addata></record> |
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| language | eng |
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| subjects | Carbonyls Chemistry Chemistry and Materials Science Chemistry/Food Science Copolymerization Copolymers Crosslinking Cyclopropane Industrial Chemistry/Chemical Engineering Macromolecular Compounds and Polymeric Materials Mathematical analysis Photoresists Photosensitivity Polymethyl methacrylate Refractivity |
| title | Copolymers based on (p-vinylphenyl)cyclopropylmethyl chlorocinnamate and methyl methacrylate |
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