Dominant Mechanisms for Metal Removal from Acidic Aqueous Solutions by Cement Kiln Dust

Copper and zinc ions were removed from synthetic acidic aqueous solutions onto cement kiln dust (CKD) particles in a single component system. The objectives of this study were to: distinguish between adsorption and precipitation when both mechanisms are occurring simultaneously; define their individual contributions; and consequently, specify the dominant mechanism. This was achieved by conducting a new experimental procedure for the precipitation phase that depended on CKD leachate in combination with a derivation of a simultaneous adsorption-precipitation equation. High removal efficiencies, approaching 100 %, of the Cu and Zn ions, were attained. Precipitation was the dominant mechanism for removing low concentrations of these metals, while adsorption appears to be more significant in removal of high metal concentrations.