High UV light performance for the degradation of Rhodamine B dye by synthesized Bi2S3ZnO nanocomposite

Heterogeneous photocatalytic degradation of organics in water and wastewater by large band gap semiconductors has offered an attractive alternative for environmental remediation. Zinc oxide is a very fast and efficient catalyst because of its wide band gap and large exciton binding energy. In this s...

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Veröffentlicht in:Applied physics. A, Materials science & processing Materials science & processing, 2017-05, Vol.123 (5), p.1-10, Article 364
Hauptverfasser: Sangareswari, M., Meenakshi Sundaram, M.
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Sprache:eng
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Zusammenfassung:Heterogeneous photocatalytic degradation of organics in water and wastewater by large band gap semiconductors has offered an attractive alternative for environmental remediation. Zinc oxide is a very fast and efficient catalyst because of its wide band gap and large exciton binding energy. In this study, an efficient Bi 2 S 3 ZnO was synthesized by sonochemical method. The obtained product was further characterized by TEM, SEM, XRD, FT-IR and UV–DRS analysis. Scanning electron microscopy images revealed that Bi 2 S 3 ZnO has flower-like structure. The synthesized flower-like Bi 2 S 3 ZnO nanocomposites were more efficient than commercial ZnO for the degradation of organic contaminants under UV light irradiation. The prepared material shows enhanced photocatalytic activity on Rhodamine B dye solution under UV light irradiation. The percentage removal of dye was calculated by UV–Vis spectrophotometer. In addition, Bi 2 S 3 ZnO showed tremendous photocatalytic stability after seven cycles under UV light irradiation. A possible mechanism for the photocatalytic oxidative degradation was also discussed. It is concluded that the Bi 2 S 3 ZnO nanocomposite acts as an excellent photocatalyst for the decomposition of RhB and it could be a potential material for essential wastewater treatment.
ISSN:0947-8396
1432-0630
DOI:10.1007/s00339-017-0969-3