High UV light performance for the degradation of Rhodamine B dye by synthesized Bi2S3ZnO nanocomposite
Heterogeneous photocatalytic degradation of organics in water and wastewater by large band gap semiconductors has offered an attractive alternative for environmental remediation. Zinc oxide is a very fast and efficient catalyst because of its wide band gap and large exciton binding energy. In this s...
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Veröffentlicht in: | Applied physics. A, Materials science & processing Materials science & processing, 2017-05, Vol.123 (5), p.1-10, Article 364 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Heterogeneous photocatalytic degradation of organics in water and wastewater by large band gap semiconductors has offered an attractive alternative for environmental remediation. Zinc oxide is a very fast and efficient catalyst because of its wide band gap and large exciton binding energy. In this study, an efficient Bi
2
S
3
ZnO was synthesized by sonochemical method. The obtained product was further characterized by TEM, SEM, XRD, FT-IR and UV–DRS analysis. Scanning electron microscopy images revealed that Bi
2
S
3
ZnO has flower-like structure. The synthesized flower-like Bi
2
S
3
ZnO nanocomposites were more efficient than commercial ZnO for the degradation of organic contaminants under UV light irradiation. The prepared material shows enhanced photocatalytic activity on Rhodamine B dye solution under UV light irradiation. The percentage removal of dye was calculated by UV–Vis spectrophotometer. In addition, Bi
2
S
3
ZnO showed tremendous photocatalytic stability after seven cycles under UV light irradiation. A possible mechanism for the photocatalytic oxidative degradation was also discussed. It is concluded that the Bi
2
S
3
ZnO nanocomposite acts as an excellent photocatalyst for the decomposition of RhB and it could be a potential material for essential wastewater treatment. |
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ISSN: | 0947-8396 1432-0630 |
DOI: | 10.1007/s00339-017-0969-3 |