Spinel LiNi0.5Mn1.5O4 Cathode for High‐Energy Aqueous Lithium‐Ion Batteries

A 2.9 V intrinsic safe aqueous LiNi0.5Mn1.5O4/Mo6S8 full cell delivers 80 W h kg−1 energy density with capacity decay of 0.075% per cycle (5 C). After the electrolyte pH value adjustment, almost full capacity of LiNi0.5Mn1.5O4 (125 mA h kg−1) is achieved, and 126 W h kg−1 energy density is provided...

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Veröffentlicht in:Advanced energy materials 2017-04, Vol.7 (8), p.n/a
Hauptverfasser: Wang, Fei, Suo, Liumin, Liang, Yujia, Yang, Chongyin, Han, Fudong, Gao, Tao, Sun, Wei, Wang, Chunsheng
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Sprache:eng
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Zusammenfassung:A 2.9 V intrinsic safe aqueous LiNi0.5Mn1.5O4/Mo6S8 full cell delivers 80 W h kg−1 energy density with capacity decay of 0.075% per cycle (5 C). After the electrolyte pH value adjustment, almost full capacity of LiNi0.5Mn1.5O4 (125 mA h kg−1) is achieved, and 126 W h kg−1 energy density is provided for LiNi0.5Mn1.5O4/Mo6S8 cell, representing one of the highest voltage and energy density among all the aqueous batteries.
ISSN:1614-6832
1614-6840
DOI:10.1002/aenm.201600922