Remarkable catalytic activity of Bi2O3/TiO2 nanocomposites prepared by hydrothermal method for the degradation of methyl orange

Visible light Bi 2 O 3 /TiO 2 nanocomposites are successfully prepared with different dosages of Bi 2 O 3 by hydrothermal process. All the as-prepared samples are characterized by X-ray diffraction (XRD), scanning and transmission electron microscopes (SEM and TEM), Brunauer-Emmett-Teller analysis (BET), N 2 adsorption-desorption measurement, and UV-Vis diffuse reflectance spectra (DRS). XRD and Raman spectra reveal the anatase phase of both TiO 2 and Bi 2 O 3 /TiO 2 nanocomposites. X-ray diffraction patterns demonstrate that the bismuth ions did not enter into the lattice of TiO 2 , and Bi 2 O 3 is extremely dispersive on the surface of TiO 2 nanoparticles. The incorporation of Bi 2 O 3 in TiO 2 leads to the spectral response of TiO 2 in the visible light region and efficient separation of charge carriers. The enhanced visible light activity is tested by the photocatalytic degradation of methyl orange under light illumination, and the performance of Bi 2 O 3 /TiO 2 nanocomposites are superior than that of pure TiO 2 which is ascribed to the efficient charge separation and transfer across the Bi 2 O 3 /TiO 2 junction. Bi 2 O 3 /TiO 2 nanocomposite (20 mg) loaded with 0.25 of Bi 2 O 3 dispersed in 50 ml of 5 ppm methyl orange solution exhibited the highest photocatalytic activity of 98.86% within 240 min of irradiation, which is attributed to the low band gap, high surface area, and the strong interaction between Bi 2 O 3 and TiO 2 .