Crystal structure of the complex of copper(II) with 3-(2-hydroxy-3-sulfo-5-nitrophenylazo)-pentadione-2,4

Crystal structure of the complex of copper(II) with 3-(2-hydroxy-3-sulfo-5-nitrophenylazo)-pentadione-2,4

A new complex of copper (II) with 3-(2-hydroxy-3-sulfo-5-nitrophenylazo)-pentadione-2,4 (HL) is synthesized and analyzed by single crystal XRD. The crystals are monoclinic: a = 7.7563(4) Å, b = 24.0157(12) Å, c = 24.6353(13) Å, β = 91.9490(10)°, V = 4586.2(4) Å 3 , space group P2 1 / c , Z = 2, ρ ca...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of structural chemistry 2016-07, Vol.57 (4), p.819-821
Hauptverfasser: Maharramov, A. M., Alieva, R. A., Nazarova, G. G., Bakhmanova, F. N., Askerov, R. K., Chyragov, F. M.
Format: Artikel
Sprache:eng
Schlagworte:
Atomic
Atomic/Molecular Structure and Spectra
Brief Communications
Chemistry
Chemistry and Materials Science
Copper
Crystal structure
Inorganic Chemistry
Molecular
Optical and Plasma Physics
Oxygen atoms
Physical Chemistry
Single crystals
Solid State Physics
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A new complex of copper (II) with 3-(2-hydroxy-3-sulfo-5-nitrophenylazo)-pentadione-2,4 (HL) is synthesized and analyzed by single crystal XRD. The crystals are monoclinic: a = 7.7563(4) Å, b = 24.0157(12) Å, c = 24.6353(13) Å, β = 91.9490(10)°, V = 4586.2(4) Å 3 , space group P2 1 / c , Z = 2, ρ calc = 1.713 g/cm 3 , R = 0.0695. The environment of the copper atom is formed by three oxygen atoms, the nitrogen atom of tetradentate ligand, and the oxygen atom of a water molecule.
ISSN:0022-4766
1573-8779
DOI:10.1134/S0022476616040296