Restructuring of the meso-methyl-substituted thiacarbocyanine aggregates in solution: Molecular nanomachines

Restructuring of the meso-methyl-substituted thiacarbocyanine aggregates in solution: Molecular nanomachines

Spontaneous transformation in the aqueous solution of the metal-complex J-aggregates of the meso -methyl-substituted thiacarbocyanine into the metal-complex H-aggregates is studied. It is concluded that the transformation of aggregates is connected with a change in the structure of their primary agg...

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Veröffentlicht in:Nanotechnologies in Russia 2016-09, Vol.11 (9-10), p.523-527
Hauptverfasser: Shapiro, B. I., Manulik, E. V.
Format: Artikel
Sprache:eng
Schlagworte:
Aqueous solutions
Brickwork
Chemistry and Materials Science
Industrial and Production Engineering
Machines
Manufacturing
Materials Science
Nanotechnology
Processes
Substitutes
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Beschreibung
Zusammenfassung:Spontaneous transformation in the aqueous solution of the metal-complex J-aggregates of the meso -methyl-substituted thiacarbocyanine into the metal-complex H-aggregates is studied. It is concluded that the transformation of aggregates is connected with a change in the structure of their primary aggregates from the monomer packing of the “brickwork” type to packing of the “ladder” type.
ISSN:1995-0780
1995-0799
DOI:10.1134/S1995078016050165