Stevens rearrangement of heterocyclic ammonium salts containing prop-2-yn-1-yl group

Stevens rearrangement of heterocyclic ammonium salts containing prop-2-yn-1-yl group

Stevens rearrangement was studied of ammonium salts where piperidinium or morpholinium groups are linked to prop-2-yn-1-yl moiety and labile hydrogen atom functions (methoxycarbonylmethyl, phenacyl, cyanomethyl). In the case of phenacyl analog furan derivatives were formed, in other cases dienamines...

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Veröffentlicht in:Russian journal of general chemistry 2016-09, Vol.86 (9), p.2067-2070
Hauptverfasser: Gyul’nazaryan, A. Kh, Sahakyan, T. A., Sargsyan, G. T., Grigoryan, J. V., Muradyan, G. M., Petrosyan, A. M., Panosyan, G. A.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Hydrogen atoms
Reaction products
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Zusammenfassung:Stevens rearrangement was studied of ammonium salts where piperidinium or morpholinium groups are linked to prop-2-yn-1-yl moiety and labile hydrogen atom functions (methoxycarbonylmethyl, phenacyl, cyanomethyl). In the case of phenacyl analog furan derivatives were formed, in other cases dienamines were the reaction products.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363216090140