1-Bromo-3,3,3-trifluoro-1-nitropropene: Synthesis and reaction with phenyl azide

1-Bromo-3,3,3-trifluoro-1-nitropropene: Synthesis and reaction with phenyl azide

An improved procedure was developed for the synthesis of 3,3,3-trifluoro-1-nitropropene, and a new representative of gem -bromonitroalkenes, 1-bromo-3,3,3-trifluoro-1-nitropropene, was synthesized therefrom. Its reaction with phenyl azide gave a mixture of two regioisomeric 1,2,3-triazoles, from whi...

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Veröffentlicht in:Russian journal of organic chemistry 2016, Vol.52 (10), p.1379-1384
Hauptverfasser: Anisimova, N. A., Slobodchikova, E. K., Kuzhaeva, A. A., Stukan’, E. V., Bagryanskaya, I. Yu, Berestovitskaya, V. M.
Format: Artikel
Sprache:eng
Schlagworte:
Azides (organic)
Chemical synthesis
Chemistry
Chemistry and Materials Science
Organic Chemistry
Triazoles
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Zusammenfassung:An improved procedure was developed for the synthesis of 3,3,3-trifluoro-1-nitropropene, and a new representative of gem -bromonitroalkenes, 1-bromo-3,3,3-trifluoro-1-nitropropene, was synthesized therefrom. Its reaction with phenyl azide gave a mixture of two regioisomeric 1,2,3-triazoles, from which pure 5-nitro-1-phenyl-4-(trifluoromethyl)-1 H -1,2,3-triazole was isolated.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428016100018