Theoretical study of low-energy electron scattering with GeH2
We present a comprehensive study of electron collisions with germylene (GeH 2 using the UK molecular R-matrix codes for electron energies ranging from 0.01 to 10 eV. The calculations are performed within the static-exchange, static-exchange-polarization, and 17-state close-coupling approximations. T...
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Veröffentlicht in: | The European physical journal. D, Atomic, molecular, and optical physics Atomic, molecular, and optical physics, 2017, Vol.71 (1), p.1-6, Article 20 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | We present a comprehensive study of electron collisions with germylene (GeH
2
using the UK molecular R-matrix codes for electron energies ranging from 0.01 to 10 eV. The calculations are performed within the static-exchange, static-exchange-polarization, and 17-state close-coupling approximations. The elastic integral, differential, momentum transfer cross sections and the excitation cross sections from the ground state to the six low-lying electron excited states are presented. We found three Feshbach resonances and one Core-excited resonance. These resonances reveal the probability of anion formation by an electron attachment process and further decay to neutral and negative ion fragments. The electronic and rotational excitation cross sections for e-GeH
2
scattering are reported for the first time. The cross-section dataset obtained from the present calculations are expected to be sufficiently accurate and comprehensive for most current modeling applications involving neutral GeH
2
.
Graphical abstract |
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ISSN: | 1434-6060 1434-6079 |
DOI: | 10.1140/epjd/e2016-70594-5 |