Visible light-induced degradation of phenolic compounds by Sudan black dye sensitized TiO2 nanoparticles as an advanced photocatalytic material
Using a simple impregnation process, the present study has introduced a novel route for the photosensitization of TiO 2 nanoparticles using Sudan black B dye as a sensitizer. DRS, XRD, FE-SEM, BET, UV–Vis, FT-IR and TGA–DSC analyses were considered for characterization of the synthesized purple powd...
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Veröffentlicht in: | Research on chemical intermediates 2017-02, Vol.43 (2), p.1197-1209 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Using a simple impregnation process, the present study has introduced a novel route for the photosensitization of TiO
2
nanoparticles using Sudan black B dye as a sensitizer. DRS, XRD, FE-SEM, BET, UV–Vis, FT-IR and TGA–DSC analyses were considered for characterization of the synthesized purple powder as a visible light photocatalyst for removal of the phenolic pollutant. The band gap of the dye-sensitized TiO
2
and corresponding BET surface area were 2.9 eV and 50.0 m
2
g
−1
, respectively. Based on the results, Sudan Black sensitized TiO
2
photocatalyst outperforms the pure commercial TiO
2
(Degussa P25) in terms of phenol degradation under visible light. Under a 100-min photo-catalytic experiment, dye-sensitized TiO
2
removed 96 % of the phenol content. The Sudan black B dye-sensitized TiO
2
is expected to show further interesting physical characteristics related to potential uses. |
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ISSN: | 0922-6168 1568-5675 |
DOI: | 10.1007/s11164-016-2692-7 |