Efficient synthetic route for thio-triazole derivatives catalyzed by iron doped fluorapatite
Novel heterogeneous iron doped fluorapatite (Fe-FAp) catalysts were prepared by co-precipitation in the presence of amino acids, glutamic acid, aspartic acid, glycine, and histidine to establish their influence on catalytic activity of Fe-FAps. The four materials, named Fe-FAp/glutamic acid, Fe-FAp/...
Gespeichert in:
| Veröffentlicht in: | Research on chemical intermediates 2017-03, Vol.43 (3), p.1793-1811 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1811 |
|---|---|
| container_issue | 3 |
| container_start_page | 1793 |
| container_title | Research on chemical intermediates |
| container_volume | 43 |
| creator | Gangu, Kranthi Kumar Maddila, Suresh Maddila, Surya Narayana Jonnalagadda, Sreekantha B. |
| description | Novel heterogeneous iron doped fluorapatite (Fe-FAp) catalysts were prepared by co-precipitation in the presence of amino acids, glutamic acid, aspartic acid, glycine, and histidine to establish their influence on catalytic activity of Fe-FAps. The four materials, named Fe-FAp/glutamic acid, Fe-FAp/aspartic acid, Fe-FAp/glycine, Fe-FAp/histidine, were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, microscopic (FE-SEM and HR-TEM) analysis, and N
2
sorption isotherms. Amino acids influenced the crystal growth and morphology of Fe-FAps differently and generated materials with diverse morphological features in size, pore properties and surface areas. The efficacy of different Fe-FAps as heterogeneous catalysts in the value added conversion of various aromatic aldehydes to thio-triazole derivatives with ethanol as solvent was investigated. For the title reaction, glutamic acid assisted Fe-FAp displayed superior activity with 96 % yield in a short-interval of times (10 min) at room temperature. Employing the optimized conditions, six different 1,2,4-triazolidine-3-thione derivatives were synthesized in excellent yields (91–96 %) at reaction temperature in |
| doi_str_mv | 10.1007/s11164-016-2730-5 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1880776784</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1880776784</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-ae7681926e0b8788b9dcb03f8a902c751b3f14c547207a2e9a60a9165ec3a4a83</originalsourceid><addsrcrecordid>eNp1kMtKxDAUhoMoOF4ewF3AdTQnbS5dyjBeYMCN7oSQpqmToTZjkg50nt4OdeHG1eHA9_-H8yF0A_QOKJX3CQBESSgIwmRBCT9BC-BCES4kP0ULWjFGBAh1ji5S2lIKXCm6QB-rtvXWuz7jNPZ547K3OIYhO9yGiPPGB5KjN4fQOdy46Pcm-71L2JpsuvHgGlyP2MfQ4ybspq3thhDNbqKyu0JnremSu_6dl-j9cfW2fCbr16eX5cOa2AJEJsZJoaBiwtFaSaXqqrE1LVplKsqs5FAXLZSWl5JRaZirjKCmAsGdLUxpVHGJbufeXQzfg0tZb8MQ--mkhulLKYVU5UTBTNkYUoqu1bvov0wcNVB9lKhniXqSqI8SNZ8ybM6kie0_XfzT_G_oB1ZYdY0</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1880776784</pqid></control><display><type>article</type><title>Efficient synthetic route for thio-triazole derivatives catalyzed by iron doped fluorapatite</title><source>SpringerLink Journals - AutoHoldings</source><creator>Gangu, Kranthi Kumar ; Maddila, Suresh ; Maddila, Surya Narayana ; Jonnalagadda, Sreekantha B.</creator><creatorcontrib>Gangu, Kranthi Kumar ; Maddila, Suresh ; Maddila, Surya Narayana ; Jonnalagadda, Sreekantha B.</creatorcontrib><description>Novel heterogeneous iron doped fluorapatite (Fe-FAp) catalysts were prepared by co-precipitation in the presence of amino acids, glutamic acid, aspartic acid, glycine, and histidine to establish their influence on catalytic activity of Fe-FAps. The four materials, named Fe-FAp/glutamic acid, Fe-FAp/aspartic acid, Fe-FAp/glycine, Fe-FAp/histidine, were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, microscopic (FE-SEM and HR-TEM) analysis, and N
2
sorption isotherms. Amino acids influenced the crystal growth and morphology of Fe-FAps differently and generated materials with diverse morphological features in size, pore properties and surface areas. The efficacy of different Fe-FAps as heterogeneous catalysts in the value added conversion of various aromatic aldehydes to thio-triazole derivatives with ethanol as solvent was investigated. For the title reaction, glutamic acid assisted Fe-FAp displayed superior activity with 96 % yield in a short-interval of times (10 min) at room temperature. Employing the optimized conditions, six different 1,2,4-triazolidine-3-thione derivatives were synthesized in excellent yields (91–96 %) at reaction temperature in <20 min time.
Graphical Abstract</description><identifier>ISSN: 0922-6168</identifier><identifier>EISSN: 1568-5675</identifier><identifier>DOI: 10.1007/s11164-016-2730-5</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Catalysis ; Catalysts ; Catalytic activity ; Chemistry ; Chemistry and Materials Science ; Crystal growth ; Infrared spectroscopy ; Inorganic Chemistry ; Physical Chemistry ; Surface area ; Triazoles</subject><ispartof>Research on chemical intermediates, 2017-03, Vol.43 (3), p.1793-1811</ispartof><rights>Springer Science+Business Media Dordrecht 2016</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-ae7681926e0b8788b9dcb03f8a902c751b3f14c547207a2e9a60a9165ec3a4a83</citedby><cites>FETCH-LOGICAL-c316t-ae7681926e0b8788b9dcb03f8a902c751b3f14c547207a2e9a60a9165ec3a4a83</cites><orcidid>0000-0001-6501-8875</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11164-016-2730-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11164-016-2730-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27922,27923,41486,42555,51317</link.rule.ids></links><search><creatorcontrib>Gangu, Kranthi Kumar</creatorcontrib><creatorcontrib>Maddila, Suresh</creatorcontrib><creatorcontrib>Maddila, Surya Narayana</creatorcontrib><creatorcontrib>Jonnalagadda, Sreekantha B.</creatorcontrib><title>Efficient synthetic route for thio-triazole derivatives catalyzed by iron doped fluorapatite</title><title>Research on chemical intermediates</title><addtitle>Res Chem Intermed</addtitle><description>Novel heterogeneous iron doped fluorapatite (Fe-FAp) catalysts were prepared by co-precipitation in the presence of amino acids, glutamic acid, aspartic acid, glycine, and histidine to establish their influence on catalytic activity of Fe-FAps. The four materials, named Fe-FAp/glutamic acid, Fe-FAp/aspartic acid, Fe-FAp/glycine, Fe-FAp/histidine, were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, microscopic (FE-SEM and HR-TEM) analysis, and N
2
sorption isotherms. Amino acids influenced the crystal growth and morphology of Fe-FAps differently and generated materials with diverse morphological features in size, pore properties and surface areas. The efficacy of different Fe-FAps as heterogeneous catalysts in the value added conversion of various aromatic aldehydes to thio-triazole derivatives with ethanol as solvent was investigated. For the title reaction, glutamic acid assisted Fe-FAp displayed superior activity with 96 % yield in a short-interval of times (10 min) at room temperature. Employing the optimized conditions, six different 1,2,4-triazolidine-3-thione derivatives were synthesized in excellent yields (91–96 %) at reaction temperature in <20 min time.
Graphical Abstract</description><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Crystal growth</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Physical Chemistry</subject><subject>Surface area</subject><subject>Triazoles</subject><issn>0922-6168</issn><issn>1568-5675</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kMtKxDAUhoMoOF4ewF3AdTQnbS5dyjBeYMCN7oSQpqmToTZjkg50nt4OdeHG1eHA9_-H8yF0A_QOKJX3CQBESSgIwmRBCT9BC-BCES4kP0ULWjFGBAh1ji5S2lIKXCm6QB-rtvXWuz7jNPZ547K3OIYhO9yGiPPGB5KjN4fQOdy46Pcm-71L2JpsuvHgGlyP2MfQ4ybspq3thhDNbqKyu0JnremSu_6dl-j9cfW2fCbr16eX5cOa2AJEJsZJoaBiwtFaSaXqqrE1LVplKsqs5FAXLZSWl5JRaZirjKCmAsGdLUxpVHGJbufeXQzfg0tZb8MQ--mkhulLKYVU5UTBTNkYUoqu1bvov0wcNVB9lKhniXqSqI8SNZ8ybM6kie0_XfzT_G_oB1ZYdY0</recordid><startdate>20170301</startdate><enddate>20170301</enddate><creator>Gangu, Kranthi Kumar</creator><creator>Maddila, Suresh</creator><creator>Maddila, Surya Narayana</creator><creator>Jonnalagadda, Sreekantha B.</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-6501-8875</orcidid></search><sort><creationdate>20170301</creationdate><title>Efficient synthetic route for thio-triazole derivatives catalyzed by iron doped fluorapatite</title><author>Gangu, Kranthi Kumar ; Maddila, Suresh ; Maddila, Surya Narayana ; Jonnalagadda, Sreekantha B.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-ae7681926e0b8788b9dcb03f8a902c751b3f14c547207a2e9a60a9165ec3a4a83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Catalysis</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Crystal growth</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Physical Chemistry</topic><topic>Surface area</topic><topic>Triazoles</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gangu, Kranthi Kumar</creatorcontrib><creatorcontrib>Maddila, Suresh</creatorcontrib><creatorcontrib>Maddila, Surya Narayana</creatorcontrib><creatorcontrib>Jonnalagadda, Sreekantha B.</creatorcontrib><collection>CrossRef</collection><jtitle>Research on chemical intermediates</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gangu, Kranthi Kumar</au><au>Maddila, Suresh</au><au>Maddila, Surya Narayana</au><au>Jonnalagadda, Sreekantha B.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Efficient synthetic route for thio-triazole derivatives catalyzed by iron doped fluorapatite</atitle><jtitle>Research on chemical intermediates</jtitle><stitle>Res Chem Intermed</stitle><date>2017-03-01</date><risdate>2017</risdate><volume>43</volume><issue>3</issue><spage>1793</spage><epage>1811</epage><pages>1793-1811</pages><issn>0922-6168</issn><eissn>1568-5675</eissn><abstract>Novel heterogeneous iron doped fluorapatite (Fe-FAp) catalysts were prepared by co-precipitation in the presence of amino acids, glutamic acid, aspartic acid, glycine, and histidine to establish their influence on catalytic activity of Fe-FAps. The four materials, named Fe-FAp/glutamic acid, Fe-FAp/aspartic acid, Fe-FAp/glycine, Fe-FAp/histidine, were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, microscopic (FE-SEM and HR-TEM) analysis, and N
2
sorption isotherms. Amino acids influenced the crystal growth and morphology of Fe-FAps differently and generated materials with diverse morphological features in size, pore properties and surface areas. The efficacy of different Fe-FAps as heterogeneous catalysts in the value added conversion of various aromatic aldehydes to thio-triazole derivatives with ethanol as solvent was investigated. For the title reaction, glutamic acid assisted Fe-FAp displayed superior activity with 96 % yield in a short-interval of times (10 min) at room temperature. Employing the optimized conditions, six different 1,2,4-triazolidine-3-thione derivatives were synthesized in excellent yields (91–96 %) at reaction temperature in <20 min time.
Graphical Abstract</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s11164-016-2730-5</doi><tpages>19</tpages><orcidid>https://orcid.org/0000-0001-6501-8875</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0922-6168 |
| ispartof | Research on chemical intermediates, 2017-03, Vol.43 (3), p.1793-1811 |
| issn | 0922-6168 1568-5675 |
| language | eng |
| recordid | cdi_proquest_journals_1880776784 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Catalysis Catalysts Catalytic activity Chemistry Chemistry and Materials Science Crystal growth Infrared spectroscopy Inorganic Chemistry Physical Chemistry Surface area Triazoles |
| title | Efficient synthetic route for thio-triazole derivatives catalyzed by iron doped fluorapatite |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-13T20%3A56%3A52IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Efficient%20synthetic%20route%20for%20thio-triazole%20derivatives%20catalyzed%20by%20iron%20doped%20fluorapatite&rft.jtitle=Research%20on%20chemical%20intermediates&rft.au=Gangu,%20Kranthi%20Kumar&rft.date=2017-03-01&rft.volume=43&rft.issue=3&rft.spage=1793&rft.epage=1811&rft.pages=1793-1811&rft.issn=0922-6168&rft.eissn=1568-5675&rft_id=info:doi/10.1007/s11164-016-2730-5&rft_dat=%3Cproquest_cross%3E1880776784%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1880776784&rft_id=info:pmid/&rfr_iscdi=true |