Synthesis and structure of allylated derivatives of fullerenes C60 and C70

Synthesis and structure of allylated derivatives of fullerenes C60 and C70

New chromatographically pure monoand hexamethanofullerenes C 60 and C 70 containing active allylic groups were synthesized by Bingel—Hirsch reaction. These compounds are promising for the studies of biological activity, as well as for obtaining on their basis new fullerenecontaining materials. The p...

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Veröffentlicht in:Russian chemical bulletin 2016-06, Vol.65 (6), p.1556-1565
Hauptverfasser: Gubskaya, V. P., Islamova, L. N., Fazleeva, G. M., Latypov, Sh. K., Saifina, A. F., Gubaidullin, A. T., Sharafutdinova, D. R., Nuretdinov, I. A., Sinyashin, O. G.
Format: Artikel
Sprache:eng
Schlagworte:
Biological activity
Buckminsterfullerene
Chemical synthesis
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Full Articles
Fullerenes
Inorganic Chemistry
Mass spectrometry
NMR spectroscopy
Organic Chemistry
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Zusammenfassung:New chromatographically pure monoand hexamethanofullerenes C 60 and C 70 containing active allylic groups were synthesized by Bingel—Hirsch reaction. These compounds are promising for the studies of biological activity, as well as for obtaining on their basis new fullerenecontaining materials. The purity and composition of the synthesized compounds were confirmed by MALDI-TOF mass spectrometry and HPLC, their structure was established by 1 H and 13 C NMR spectroscopy and X-ray diffraction.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-016-1482-0