A new ligand system containing sulfanilamide and quinazolinone fragments: Synthesis, structure, and properties

A new ligand system containing sulfanilamide and quinazolinone fragments: Synthesis, structure, and properties

A new Schiff base ligand, 4-methyl- N -{2-[(2-methyl-4-oxo-3,4-dihydroquinazolin-3-yl)iminomethyl]-phenyl}benzenesulfonamide (L), and its complexes with transition metals [Cd(L) 2 ], [Zn(L) 2 ], and [CuLOAc] have been synthesized. The structure and electronic properties of the ligand have been studi...

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Veröffentlicht in:Russian journal of general chemistry 2017, Vol.87 (1), p.66-75
Hauptverfasser: Popov, L. D., Borodkin, S. A., Tsaturyan, A. A., Tupolova, Yu. P., Levchenkov, S. I., Minin, V. V., Burlov, A. S., Revinskii, Yu. V., Shcherbakov, I. N., Raspopova, E. A.
Format: Artikel
Sprache:eng
Schlagworte:
Chemical synthesis
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Imines
Ligands
Luminescence
Optical properties
Quantum chemistry
Transition metals
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Zusammenfassung:A new Schiff base ligand, 4-methyl- N -{2-[(2-methyl-4-oxo-3,4-dihydroquinazolin-3-yl)iminomethyl]-phenyl}benzenesulfonamide (L), and its complexes with transition metals [Cd(L) 2 ], [Zn(L) 2 ], and [CuLOAc] have been synthesized. The structure and electronic properties of the ligand have been studied by quantum chemical methods, and its zinc and cadmium complexes have been found to exhibit luminescence properties.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363217010121