Photochemical cyclocondensation of 1-arylthio-2-azidoanthraquinones with phenols

Photochemical cyclocondensation of 1-arylthio-2-azidoanthraquinones with phenols

Photolysis of 1-arylthio-2-azidoanthraquinones in DMSO in the presence of phenols leads to the formation of 5 H -naphtho[2,3- c ]phenothiazine-8,13-diones, in which the nitrogen atom is covalently bonded with the phenyl ring of the introduced phenol. As a result, poorly available polycyclic phenothi...

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Veröffentlicht in:Russian chemical bulletin 2016-07, Vol.65 (7), p.1814-1819
Hauptverfasser: Klimenko, L. S., Sirazhetdinova, N. S., Savel’ev, V. A., Martyanov, T. P., Korchagin, D. V.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Full Articles
Inorganic Chemistry
Organic Chemistry
Phenols
Photolysis
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Zusammenfassung:Photolysis of 1-arylthio-2-azidoanthraquinones in DMSO in the presence of phenols leads to the formation of 5 H -naphtho[2,3- c ]phenothiazine-8,13-diones, in which the nitrogen atom is covalently bonded with the phenyl ring of the introduced phenol. As a result, poorly available polycyclic phenothiazine derivatives were obtained in one step in high yields. The cyclo-condensation with phenols was found to proceed only photochemically.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-016-1515-8