Various flowsheets of actinides recovery with diamides of heterocyclic dicarboxylic acids

Solvents on the base of diamides of heterocyclic dicarboxylic acids are promising alternatives for studied Grouped ActiNide EXtraction (GANEX) solvents. Advantage of these ligands is the possibility of simultaneous extraction not only of residual uranium and plutonium, but also minor actinides—neptu...

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Veröffentlicht in:Journal of radioanalytical and nuclear chemistry 2017-04, Vol.312 (1), p.47-58
Hauptverfasser: Alyapyshev, Mikhail, Babain, Vasiliy, Tkachenko, Lyudmila
Format: Artikel
Sprache:eng
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Zusammenfassung:Solvents on the base of diamides of heterocyclic dicarboxylic acids are promising alternatives for studied Grouped ActiNide EXtraction (GANEX) solvents. Advantage of these ligands is the possibility of simultaneous extraction not only of residual uranium and plutonium, but also minor actinides—neptunium, americium and curium. Two flowsheets on the base of diamides of heterocyclic dicarboxylic acids for separation of actinides form acidic solutions were developed, tested in laboratory scale and compared. Both flowsheets allow separation of more than 99.95% of actinides from raffinates with high content of lanthanides.
ISSN:0236-5731
1588-2780
DOI:10.1007/s10967-017-5194-1