Synthesis and Radical Polymerization of Acrylamides Having One or Two 3-Carbazolylmethyl Moieties and Properties of the Formed Polymers

Synthesis and Radical Polymerization of Acrylamides Having One or Two 3-Carbazolylmethyl Moieties and Properties of the Formed Polymers

A series of novel mono- and bis[(9-alkylcarbazol-3-yl)methyl]acrylamides were synthesized and their radical polymerization was investigated. Emissions of bis(carbazolyl)acrylamide polymers were extended to longer wavelengths compared with those of the corresponding mono(carbazolyl) polymers, indicat...

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Veröffentlicht in:Chemistry letters 2017-01, Vol.46 (1), p.85-87
Hauptverfasser: Tani, Keita, Kato, Haruka, Sakata, Naoya, Yashima, Toru, Kubono, Koji, Hori, Kazushige, Tao, Keisuke, Goto, Kenta, Tani, Fumito, Takemura, Hiroyuki, Sakakibara, Keita, Tsujii, Yoshinobu
Format: Artikel
Sprache:eng
Schlagworte:
Carbazoles
Chemical synthesis
Ionization potentials
Photoelectrons
Polyacrylamide
Polymerization
Polymers
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Zusammenfassung:A series of novel mono- and bis[(9-alkylcarbazol-3-yl)methyl]acrylamides were synthesized and their radical polymerization was investigated. Emissions of bis(carbazolyl)acrylamide polymers were extended to longer wavelengths compared with those of the corresponding mono(carbazolyl) polymers, indicating the existence of interchromophoric interaction between carbazole moieties. Ionization potentials of the polymers by photoelectron yield spectroscopy showed that donor ability of the biscarbazolyl polymer was higher than that of the monocarbazolyl polymer.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.160899