Cover Picture: Halogen‐Bonded Supramolecular Capsules in the Solid State, in Solution, and in the Gas Phase (Angew. Chem. Int. Ed. 4/2017)

Halogen‐bonded supramolecular capsules … … were investigated in the solid state, in solution, and in the gas phase. In their Communication on page 1152 ff. F. Diederich and co‐workers describe the first X‐ray crystal structure of a discrete, neutral, dimeric capsule assembled solely by halogen bondi...

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Veröffentlicht in:Angewandte Chemie International Edition 2017-01, Vol.56 (4), p.909-909
Hauptverfasser: Dumele, Oliver, Schreib, Benedikt, Warzok, Ulrike, Trapp, Nils, Schalley, Christoph A., Diederich, François
Format: Artikel
Sprache:eng
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Zusammenfassung:Halogen‐bonded supramolecular capsules … … were investigated in the solid state, in solution, and in the gas phase. In their Communication on page 1152 ff. F. Diederich and co‐workers describe the first X‐ray crystal structure of a discrete, neutral, dimeric capsule assembled solely by halogen bonding. Tuning the halogen bonding donor with iodoethynyl leads to the highest reported association constant for neutral halogen bonding interactions in solution.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201611992