Synthesis, Characterization and Properties of N-Alkyl-N,N-di(2-hydroxyethyl) Amine Oxides
N -Dodecyl- N , N -di(2-hydroxyethyl) amine oxide (C 12 DHEAO) and N -stearyl- N , N -di(2-hydroxyethyl) amine oxide (C 18 DHEAO) were synthesized with N -alkyl-diethanolamine and hydrogen peroxide. Their chemical structures were confirmed using 1 H-NMR spectra, mass spectral fragmentation and FTIR...
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Veröffentlicht in: | Journal of surfactants and detergents 2017, Vol.20 (1), p.129-136 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
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Zusammenfassung: | N
-Dodecyl-
N
,
N
-di(2-hydroxyethyl) amine oxide (C
12
DHEAO) and
N
-stearyl-
N
,
N
-di(2-hydroxyethyl) amine oxide (C
18
DHEAO) were synthesized with
N
-alkyl-diethanolamine and hydrogen peroxide. Their chemical structures were confirmed using
1
H-NMR spectra, mass spectral fragmentation and FTIR spectroscopic analysis. It was found that C
12
DHEAO and C
18
DHEAO reduced the surface tension of water to a minimum value of approximately 28.75 mN m
−1
at concentration of 2.48 × 10
−3
mol L
−1
and 32.45 mN m
−1
at concentration of 5.21 × 10
−5
mol L
−1
, respectively. The minimum interfacial tension (IFT
min
) and the dynamic interfacial tension (DIT) of oil–water system were measured. When C
18
DHEAO concentration was in the range of 0.1–0.5%, the IFT
min
between liquid paraffin and C
18
DHEAO solutions all reached the ultra-low interfacial tension. Furthermore, their foam properties were investigated by Ross-Miles method, and the height of foam of C
12
DHEAO was 183 mm. It was also found that they showed strong emulsifying power. |
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ISSN: | 1097-3958 1558-9293 |
DOI: | 10.1007/s11743-016-1900-1 |