ChemInform Abstract: Expanding the Scope of the Babler—Dauben Oxidation: 1,3‐Oxidative Transposition of Secondary Allylic Alcohols

ChemInform Abstract: Expanding the Scope of the Babler—Dauben Oxidation: 1,3‐Oxidative Transposition of Secondary Allylic Alcohols

The newly developed robust system for the 1,3‐oxidative transposition of readily accessible aromatic allylic alcohols affords exclusively (E)‐cinnamaldehydes in high yields.

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Veröffentlicht in:ChemInform 2016-12, Vol.47 (51), p.no-no
Hauptverfasser: Killoran, Patrick M., Rossington, Steven B., Wilkinson, James A., Hadfield, John A.
Format: Artikel
Sprache:eng
Schlagworte:
Alcohol
aldehydes (acyclic compounds)
e/z‐selectivity (incl. e/z‐isomerism)
oxidation, dehydrogenation
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Zusammenfassung:The newly developed robust system for the 1,3‐oxidative transposition of readily accessible aromatic allylic alcohols affords exclusively (E)‐cinnamaldehydes in high yields.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201651076