ChemInform Abstract: Sigmatropic Rearrangement of Vinyl Aziridines: Expedient Synthesis of Cyclic Sulfoximines from Chiral Sulfinimines

ChemInform Abstract: Sigmatropic Rearrangement of Vinyl Aziridines: Expedient Synthesis of Cyclic Sulfoximines from Chiral Sulfinimines

A novel rearrangement of 2‐vinyl aziridine 2‐carboxylates to unusual chiral cyclic sulfoximines is described.

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Veröffentlicht in:ChemInform 2016-12, Vol.47 (51), p.no-no
Hauptverfasser: Moragas, Toni, Liffey, Ryan M., Regentova, Dominika, Ward, Jon‐Paul S., Dutton, Justine, Lewis, William, Churcher, Ian, Walton, Lesley, Souto, Jose A., Stockman, Robert A.
Format: Artikel
Sprache:eng
Schlagworte:
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
rearrangements
ring closure reactions, annulation reactions
thiazine derivatives
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Zusammenfassung:A novel rearrangement of 2‐vinyl aziridine 2‐carboxylates to unusual chiral cyclic sulfoximines is described.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201651183