ChemInform Abstract: Cooperative N‐Heterocyclic Carbene/Palladium‐Catalyzed Enantioselective Umpolung Annulations

The regioselective title reaction between vinyl benzoxazinanones and aryl, alkenyl or alkyl substituted enals delivers benzazepine derivatives in high yields, with high diastereo‐ and excellent enantioselectivities.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2016-11, Vol.47 (50), p.no-no
Hauptverfasser:	Guo, Chang, Fleige, Mirco, Janssen‐Mueller, Daniel, Daniliuc, Constantin G., Glorius, Frank
Format:	Artikel
Sprache:	eng
Schlagworte:	catalysis, phase‐transfer catalysis diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) multi‐membered N‐heterocycles
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Beschreibung
Zusammenfassung:	The regioselective title reaction between vinyl benzoxazinanones and aryl, alkenyl or alkyl substituted enals delivers benzazepine derivatives in high yields, with high diastereo‐ and excellent enantioselectivities.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201650153