ChemInform Abstract: Asymmetric Induction at Remote Quaternary Centers of Cyclohexadienones by Rhodium‐Catalyzed Conjugate Hydrosilylation
An enantioselective conjugate hydrosilylation of prochiral γ,γ‐disubstituted cyclohexadienones furnishes cyclohexenones with a chiral quaternary γ‐carbon atom.
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| Veröffentlicht in: | ChemInform 2016-09, Vol.47 (41), p.no-no |
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| container_title | ChemInform |
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| creator | Naganawa, Yuki Kawagishi, Mayu Ito, Jun‐ichi Nishiyama, Hisao |
| description | An enantioselective conjugate hydrosilylation of prochiral γ,γ‐disubstituted cyclohexadienones furnishes cyclohexenones with a chiral quaternary γ‐carbon atom. |
| doi_str_mv | 10.1002/chin.201641026 |
| format | Article |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | catalysis, phase‐transfer catalysis cyclohexane derivatives diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) hydrosilylation, silylation, phosphorylation spirocyclic compounds (heterocyclic compounds) spirocyclic compounds (isocyclic compounds) |
| title | ChemInform Abstract: Asymmetric Induction at Remote Quaternary Centers of Cyclohexadienones by Rhodium‐Catalyzed Conjugate Hydrosilylation |
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