ChemInform Abstract: Asymmetric Induction at Remote Quaternary Centers of Cyclohexadienones by Rhodium‐Catalyzed Conjugate Hydrosilylation

ChemInform Abstract: Asymmetric Induction at Remote Quaternary Centers of Cyclohexadienones by Rhodium‐Catalyzed Conjugate Hydrosilylation

An enantioselective conjugate hydrosilylation of prochiral γ,γ‐disubstituted cyclohexadienones furnishes cyclohexenones with a chiral quaternary γ‐carbon atom.

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Veröffentlicht in:ChemInform 2016-09, Vol.47 (41), p.no-no
Hauptverfasser: Naganawa, Yuki, Kawagishi, Mayu, Ito, Jun‐ichi, Nishiyama, Hisao
Format: Artikel
Sprache:eng
Schlagworte:
catalysis, phase‐transfer catalysis
cyclohexane derivatives
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
hydrosilylation, silylation, phosphorylation
spirocyclic compounds (heterocyclic compounds)
spirocyclic compounds (isocyclic compounds)
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Beschreibung
Zusammenfassung:An enantioselective conjugate hydrosilylation of prochiral γ,γ‐disubstituted cyclohexadienones furnishes cyclohexenones with a chiral quaternary γ‐carbon atom.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201641026