ChemInform Abstract: N‐Vinyl‐2‐(trifluoroacetylethynyl)pyrroles and E‐2‐(1‐Bromo‐2‐trifluoroacetylethenyl)pyrroles: Cross‐Coupling vs. Addition During C—H‐Functionalization of Pyrroles with Bromotrifluoroacetylacetylene in Solid Al2O3 Medium. H‐Bonding Control

ChemInform Abstract: N‐Vinyl‐2‐(trifluoroacetylethynyl)pyrroles and E‐2‐(1‐Bromo‐2‐trifluoroacetylethenyl)pyrroles: Cross‐Coupling vs. Addition During C—H‐Functionalization of Pyrroles with Bromotrifluoroacetylacetylene in Solid Al2O3 Medium. H‐Bonding Control

Depending on the substituent character at the nitrogen atom, pyrroles react acetylene (II) in two different directions.

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Veröffentlicht in:ChemInform 2016-09, Vol.47 (39), p.no-no
Hauptverfasser: Tomilin, Denis N., Gotsko, Maxim D., Sobenina, Lyubov N., Ushakov, Igor A., Afonin, Andrey V., Soshnikov, Dmitri Yu, Trofimov, Alexander B., Koldobsky, Andrey B., Trofimov, Boris A.
Format: Artikel
Sprache:eng
Schlagworte:
addition reactions
C‐C bond formation
fused pyrrole derivatives
pyrrole derivatives
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Zusammenfassung:Depending on the substituent character at the nitrogen atom, pyrroles react acetylene (II) in two different directions.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201639123