ChemInform Abstract: Regioselective Lithium—Iodine Exchange‐Initiated Cleavage of 2‐Iodomethyl‐1,3‐dioxanes: A Complex‐Induced Proximity Effect

The fragmentation of 4‐substituted 2‐iodomethyl‐1,3‐dioxanes proceeds rapidly and regioselectively to afford enol ether alcohols by preferential cleavage of the less congested C(2)—O(1) bond.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2016-08, Vol.47 (37), p.no-no
Hauptverfasser:	Bailey, William F., Fair, Justin D.
Format:	Artikel
Sprache:	eng
Schlagworte:	alcohols (acyclic compounds) cleavage reactions, decomposition reactions, pyrolysis regioselective reactions
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The fragmentation of 4‐substituted 2‐iodomethyl‐1,3‐dioxanes proceeds rapidly and regioselectively to afford enol ether alcohols by preferential cleavage of the less congested C(2)—O(1) bond.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201637018