ChemInform Abstract: Highly Selective Catalytic trans‐Hydroboration of Alkynes Mediated by Borenium Cations and B(C6F5)3

ChemInform Abstract: Highly Selective Catalytic trans‐Hydroboration of Alkynes Mediated by Borenium Cations and B(C6F5)3

Utilization of highly Lewis‐acidic boranes allows for transition metal‐free hydroboration of (hetero)aryl‐ and vinyl substituted terminal alkynes.

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Bibliographische Detailangaben
Veröffentlicht in:ChemInform 2016-08, Vol.47 (36), p.no-no
Hauptverfasser: McGough, John S., Butler, Samuel M., Cade, Ian A., Ingleson, Michael J.
Format: Artikel
Sprache:eng
Schlagworte:
alkenes (benzene compounds)
e/z‐selectivity (incl. e/z‐isomerism)
hydroboration, boration
organo‐boron compounds
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Beschreibung
Zusammenfassung:Utilization of highly Lewis‐acidic boranes allows for transition metal‐free hydroboration of (hetero)aryl‐ and vinyl substituted terminal alkynes.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201636168