Insights into the Interface Between the Electrolytic Solution and the Gold Core in Molecular Au25 Clusters

We used a large series of Au25(SCnH2n+1)180 clusters (n=2, 3, 4, 5, 6, 8, 10, 12, 14, 16, 18) to study the effect of n and the presence of electrolytes on the redox potentials. The electrochemical results were analyzed in the framework of concentric‐capacitor models that were previously proposed to...

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Veröffentlicht in:	ChemElectroChem 2016-08, Vol.3 (8), p.1237-1244
Hauptverfasser:	Antonello, Sabrina, Dainese, Tiziano, De Nardi, Marco, Perotti, Lorena, Maran, Flavio
Format:	Artikel
Sprache:	eng
Schlagworte:	cluster compounds gold interfaces Ligands nanocapacitors redox potentials
Online-Zugang:	Volltext
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