ChemInform Abstract: A Palladium‐Catalyzed Double Carbonylation Approach to Isatins from 2‐Iodoanilines

ChemInform Abstract: A Palladium‐Catalyzed Double Carbonylation Approach to Isatins from 2‐Iodoanilines

The Pd‐catalyzed double carbonylation of 2‐iodoanilines using nearly stoichiometric amounts of CO, generated ex situ from solid CO‐surrogate SilaCogen, followed by acid promoted cyclization of intermediates (IV) affords isatine derivatives.

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Veröffentlicht in:ChemInform 2016-08, Vol.47 (34), p.no-no
Hauptverfasser: Laursen, Simon R., Jensen, Mikkel T., Lindhardt, Anders T., Jacobsen, Mikkel F., Skrydstrup, Troels
Format: Artikel
Sprache:eng
Schlagworte:
carbonylation
catalysis, phase‐transfer catalysis
indole derivatives, isoindole derivatives
ring closure reactions, annulation reactions
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Zusammenfassung:The Pd‐catalyzed double carbonylation of 2‐iodoanilines using nearly stoichiometric amounts of CO, generated ex situ from solid CO‐surrogate SilaCogen, followed by acid promoted cyclization of intermediates (IV) affords isatine derivatives.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201634115