ChemInform Abstract: Oxy‐Allyl Cation Catalysis: An Enantioselective Electrophilic Activation Mode

ChemInform Abstract: Oxy‐Allyl Cation Catalysis: An Enantioselective Electrophilic Activation Mode

Using a new amino alcohol catalyst, the enantioselective conversion of racemic α‐tosyloxy ketones into optically enriched α‐indolic carbonyls in the presence of electron‐rich indole nucleophiles is investigated.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:ChemInform 2016-07, Vol.47 (33), p.no-no
Hauptverfasser: Liu, Chun, Oblak, E. Zachary, Vander Wal, Mark N., Dilger, Andrew K., Almstead, Danielle K., MacMillan, David W. C.
Format: Artikel
Sprache:eng
Schlagworte:
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
indole derivatives, isoindole derivatives
substitution reactions
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Using a new amino alcohol catalyst, the enantioselective conversion of racemic α‐tosyloxy ketones into optically enriched α‐indolic carbonyls in the presence of electron‐rich indole nucleophiles is investigated.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201633130