ChemInform Abstract: Synthesis of Enantiopure Piperazines via Asymmetric Lithiation—Trapping of N‐Boc Piperazines: Unexpected Role of the Electrophile and Distal N‐Substituent

Yield and stereoselectivity in these reactions are controlled by the electrophile and the distal N‐substituent of piperazine.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2016-07, Vol.47 (30), p.no-no
Hauptverfasser:	Firth, James D., O'Brien, Peter, Ferris, Leigh
Format:	Artikel
Sprache:	eng
Schlagworte:	C‐C bond formation diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) organo‐tin compounds oxazole derivatives pyrazine derivatives sulfuration, sulfonation, S‐alkylation Trapping
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Beschreibung
Zusammenfassung:	Yield and stereoselectivity in these reactions are controlled by the electrophile and the distal N‐substituent of piperazine.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201630204