ChemInform Abstract: Proton‐Promoted and Anion‐Enhanced Epoxidation of Olefins by Hydrogen Peroxide in the Presence of Nonheme Manganese Catalysts

A mononuclear nonheme manganese(II) complex bearing a tetradentate N4 ligand is found to be an efficient catalyst in the epoxidation of olefins by aqueous H2O2 in the presence of H2SO4.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2016-06, Vol.47 (28), p.no-no
Hauptverfasser:	Miao, Chengxia, Wang, Bin, Wang, Yong, Xia, Chungu, Lee, Yong‐Min, Nam, Wonwoo, Sun, Wei
Format:	Artikel
Sprache:	eng
Schlagworte:	catalysis, phase‐transfer catalysis diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) epoxidation oxirane derivatives
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Beschreibung
Zusammenfassung:	A mononuclear nonheme manganese(II) complex bearing a tetradentate N4 ligand is found to be an efficient catalyst in the epoxidation of olefins by aqueous H2O2 in the presence of H2SO4.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201628125