Improvement of Synthesis and Dielectric Properties of Polyurethane/Mt-QASs^sup +^ (Novel Synthesis)

Polyurethane-based nanocomposites were prepared and their dielectric properties were characterized. Polyurethane (PU) composites were prepared with different organoclay content (1, 3, 5, and 10 wt% for all cases). The composites included quaternary ammonium salts such as 1-methyl-di-octyl-1 phenyl a...

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Veröffentlicht in:Journal of polymers and the environment 2016-06, Vol.24 (2), p.139
Hauptverfasser: Baysal, Gülay, Aydin, Haluk, Hosgören, Halil, Uzan, Serhat, Karaer, Hatice
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Sprache:eng
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Zusammenfassung:Polyurethane-based nanocomposites were prepared and their dielectric properties were characterized. Polyurethane (PU) composites were prepared with different organoclay content (1, 3, 5, and 10 wt% for all cases). The composites included quaternary ammonium salts such as 1-methyl-di-octyl-1 phenyl ammonium iodide (QAS-1), 1-methyl-di-nonyl-1 phenyl ammonium iodide (QAS-2), and 1-methyl-di-dodecyl-1 phenyl ammonium iodide (QAS-3) which were newly synthesized for modification of Na+-montmorillonite. Addition of aluminum silicate enhanced the dielectric properties at a constant concentration. Dielectric constants of nanocomposites compounded with 3 %- and 5 %-organoclay were close in value. The characterization of PU/organoclay composites was carried out using Fourier transform infrared and X-ray diffraction.
ISSN:1566-2543
1572-8919
DOI:10.1007/s10924-016-0756-9